Reaction: vinylacetyl-CoA = (E)-but-2-enoyl-CoA
Glossary: (E)-but-2-enoyl-CoA = crotonyl-CoA
Other name(s): vinylacetyl coenzyme A Δ-isomerase; vinylacetyl coenzyme A isomerase; Δ3-cis-Δ2-trans-enoyl-CoA isomerase
Systematic name: vinylacetyl-CoA Δ3-Δ2-isomerase
Comments: Also acts on 3-methyl-vinylacetyl-CoA.
Links to other databases: BRENDA, EXPASY, KEGG, Metacyc, PDB, CAS registry number: 9023-73-8
References:
1. Lynen, F., Knappe, J., Lorch, E., Jütting, G. and Ringelmann, E. Die biochemische Funktion des Biotins. Angew. Chem. 71 (1959) 481-486.
2. Rilling, H.C. and Coon, M.J. The enzymatic isomerization of α-methylvinylacetyl coenzyme A and the specificity of a bacterial α-methylcrotonyl coenzyme A carboxylase. J. Biol. Chem. 235 (1960) 3087-3092.